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A 50.0-mL sample of a 0.100 M solution of a weak acid HA has an equilibrium pH of 4.00.After 1.0× 10-3mol of a substance X is added to the solution,it is observed that the pH of the solution increases.What might be true about substance X? I.X might be a strong base that partially neutralized some weak acid. II) X might be a strong acid that made the solution more acidic. III) X might be a soluble ionic compound containing the anion A-.


A) I only
B) II only
C) III only
D) I or III
E) II or III

F) A) and B)
G) A) and C)

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Which is included in the Ksp expression? I.Concentration of cation II) Concentration of anion III) Concentration of solid


A) I only
B) II only
C) III only
D) I and II
E) I,II and III

F) A) and B)
G) C) and E)

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Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH.Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH.Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.)    A)    B)    C)    D)    E)


A) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH.Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.)    A)    B)    C)    D)    E)
B) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH.Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.)    A)    B)    C)    D)    E)
C) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH.Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.)    A)    B)    C)    D)    E)
D) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH.Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.)    A)    B)    C)    D)    E)
E) Suppose 50.0 mL of a 0.100 M solution of the weak acid HA is titrated with a 0.100 M solution of NaOH.Which diagram best represents the equilibrium composition of the solution at point X on the titration curve below? (Solvent water molecules are omitted for clarity.)    A)    B)    C)    D)    E)

F) A) and E)
G) B) and E)

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The molar solubility of manganese(II) carbonate is 4.2 × 10-6 M.What is Ksp for this compound?


A) 4.2 × 10-6
B) 8.4 × 10-6
C) 3.0 × 10-16
D) 1.8 × 10-11
E) 2.0 × 10-3

F) C) and D)
G) All of the above

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Which indicator would be the best to use if 0.050 M benzoic acid (Ka = 6.6 × 10-5) is titrated with 0.050 M NaOH?


A) bromphenol blue,pH range: 3.0 - 4.5
B) bromcresol green,pH range: 3.8 - 5.4
C) alizarin,pH range: 5.7 - 7.2
D) phenol red,pH range: 6.9 - 8.5

E) All of the above
F) A) and B)

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Suppose 3.0 ×10-3 mol of NaOH are added to 6.0 ×10-3 mol of the weak acid HA.Which is the best representation of the final solution at equilibrium? (Each circle represents 1.0 ×10-3 mol of atoms,and the volume of each box is 1.0 L.Solvent water molecules are omitted for clarity.)


A) Suppose 3.0 ×10<sup>-3</sup> mol of NaOH are added to 6.0 ×10<sup>-3</sup> mol of the weak acid HA.Which is the best representation of the final solution at equilibrium? (Each circle represents 1.0 ×10<sup>-3</sup> mol of atoms,and the volume of each box is 1.0 L.Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)
B) Suppose 3.0 ×10<sup>-3</sup> mol of NaOH are added to 6.0 ×10<sup>-3</sup> mol of the weak acid HA.Which is the best representation of the final solution at equilibrium? (Each circle represents 1.0 ×10<sup>-3</sup> mol of atoms,and the volume of each box is 1.0 L.Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)
C) Suppose 3.0 ×10<sup>-3</sup> mol of NaOH are added to 6.0 ×10<sup>-3</sup> mol of the weak acid HA.Which is the best representation of the final solution at equilibrium? (Each circle represents 1.0 ×10<sup>-3</sup> mol of atoms,and the volume of each box is 1.0 L.Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)
D) Suppose 3.0 ×10<sup>-3</sup> mol of NaOH are added to 6.0 ×10<sup>-3</sup> mol of the weak acid HA.Which is the best representation of the final solution at equilibrium? (Each circle represents 1.0 ×10<sup>-3</sup> mol of atoms,and the volume of each box is 1.0 L.Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)
E) Suppose 3.0 ×10<sup>-3</sup> mol of NaOH are added to 6.0 ×10<sup>-3</sup> mol of the weak acid HA.Which is the best representation of the final solution at equilibrium? (Each circle represents 1.0 ×10<sup>-3</sup> mol of atoms,and the volume of each box is 1.0 L.Solvent water molecules are omitted for clarity.)  A)    B)    C)    D)    E)

F) B) and C)
G) A) and D)

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What is the pH of a buffer that consists of 0.45 M CH3COOH and 0.35 M CH3COONa? [Ka(CH3COOH) = 1.8 × 10-5]


A) 3.43
B) 4.64
C) 4.85
D) 4.74
E) 6.06

F) None of the above
G) A) and D)

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Which is more soluble in an acidic solution than in pure water?


A) CH3CH2OH,ethanol
B) Li2O
C) C6H12O6,glucose
D) CCl4
E) ICl3

F) A) and B)
G) A) and C)

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Suppose 0.015 mol of KOH is added to 1.00 L of 0.0010 M Ca(NO3) 2.Which statement is correct? [Ksp(Ca(OH) 2) = 6.5 × 10-6]


A) Calcium hydroxide precipitates until the solution is saturated.
B) The solution is unsaturated and no precipitate forms.
C) The concentration of calcium ions is reduced by the addition of the hydroxide ions.
D) Potassium nitrate precipitates until the solution is saturated.
E) The presence of KOH will raise the solubility of Ca(NO3) 2.

F) B) and C)
G) B) and E)

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Which of the following is correct?


A) Solubility is the concentration of unsaturated ions in solution.
B) Ksp is the same as the solubility.
C) Ksp is an equilibrium constant and solubility is the concentration of a saturated solution.
D) Ksp is the solubility product constant for a precipitate.
E) Solubility = Kw × Ksp.

F) All of the above
G) D) and E)

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Will a precipitate (ppt) form when 300.0 mL of 5.0 × 10-5M AgNO3 are added to 200.0 mL of 2.5 × 10-7M NaBr? Answer yes or no,and identify the precipitate if there is one.


A) Yes,the ppt is AgNO3(s) .
B) Yes,the ppt is AgBr(s) .
C) Yes,the ppt is NaBr(s) .
D) Yes,the ppt is NaNO3(s) .
E) No,a precipitate will not form.

F) A) and B)
G) B) and E)

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When a weak acid is titrated with a weak base,the pH at the equivalence point


A) is greater than 7.0.
B) is equal to 7.0.
C) is less than 7.0.
D) is determined by the magnitudes of Ka and Kb.
E) depends on the pKa of the indicator.

F) A) and B)
G) B) and C)

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A 20.0-mL sample of 0.25 M HNO3 is titrated with 0.15 M NaOH.What is the pH of the solution after 30.0 mL of NaOH have been added to the acid?


A) 2.00
B) 1.60
C) 1.05
D) 1.00
E) 0.00

F) All of the above
G) A) and D)

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After 50.0 mL of a 0.100 M solution of NaOH is added to 50.0 mL of a 0.100 M solution of an unknown acid,the equilibrium pH is basic.What may be concluded about the identity of the acid?


A) The acid can only be a strong monoprotic acid.
B) The acid can only be a weak monoprotic acid.
C) The acid must be a strong acid,but could be either monoprotic,diprotic,or polyprotic.
D) The acid must be a weak acid,but could be either monoprotic,diprotic,or polyprotic.
E) The acid could be either a strong or weak acid,and could be either a monoprotic,diprotic,orpolyprotic acid.

F) A) and B)
G) D) and E)

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You have 500.0 mL of a buffer solution containing 0.20 M acetic acid (CH3COOH) and 0.30 M sodium acetate (CH3COONa) .What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka(CH3COOH) = 1.8 × 10-5]


A) 4.41
B) 4.74
C) 4.56
D) 4.92
E) 5.07

F) A) and E)
G) D) and E)

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Which pair of substances cannot form a buffered aqueous solution?


A) HCN and KCN
B) NH3 and (NH4) 2SO4
C) HNO3 and NaNO3
D) HF and NaF
E) HNO2 and NaNO2

F) A) and B)
G) A) and D)

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Which best describes the pH at the equivalence point of a titration of a weak base with a strong acid?


A) Less than zero
B) Between 0 and 7
C) Close to 7.0
D) Between 7 and 14
E) Greater than 14

F) C) and E)
G) B) and D)

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When sodium acetate is added to a solution of acetic acid,what happens to the pH of the solution? Explain why this effect occurs? CH3COOH(aq) When sodium acetate is added to a solution of acetic acid,what happens to the pH of the solution? Explain why this effect occurs? CH<sub>3</sub>COOH(aq)   H<sup>+</sup>(aq)CH<sub>3</sub>COO<sup>-</sup>(aq) H+(aq)CH3COO-(aq)

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The pH increases because the equilibrium...

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If 50.0 mL of 1.2 × 10-3 M Pb(NO3) 2 are added to 50.0 mL of 2.0 × 10-4 M Na2S,what takes place?


A) A precipitate of PbS forms.
B) A precipitate of NaNO3 forms.
C) A precipitate of Na2S forms.
D) A precipitate of Pb(NO3) 2 forms.
E) No precipitate forms.

F) D) and E)
G) A) and B)

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A mixture made of 100 mL of 0.5 M CH3COOH and 100 mL of 0.5 M CH3COONa is classified as a buffer solution.

A) True
B) False

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