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Lightning, fires, and other atmospheric processes result in the formation of nitric acid, HNO3, from atmospheric N2, O2, and H2O. Write balanced chemical equations to represent the three reactions involved in the formation of HNO3 by this route.

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N2(g) + O2(g) 2...

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Transition elements from the right side of the periodic table are generally found as


A) sulfides because they tend to give up bonding electrons and form crystals with high lattice energies with sulfur.
B) sulfides because their electronegativities favor formation of covalent bonds with the polarizable sulfide anion.
C) oxides because they tend to give up bonding electrons and form crystals with high lattice energies with oxygen.
D) oxides because oxygen, with its high electronegativity, forms strong covalent bonds with them.
E) none of the above

F) D) and E)
G) A) and D)

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The industrial production of ammonia from nitrogen and hydrogen accounts for a greater amount of nitrogen fixation than either the atmospheric or the biological pathways.

A) True
B) False

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False

Carbon atoms in the carbon cycle spend most of their time in the oceans.

A) True
B) False

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The most common source for commercial production of aluminum is called


A) aluminite.
B) hematite.
C) galena.
D) cinnabar.
E) bauxite.

F) A) and B)
G) A) and C)

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The most abundant element in the Earth's crust is


A) H.
B) Fe.
C) Al.
D) Si.
E) O.

F) All of the above
G) B) and D)

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The Earth's core consists mainly of


A) Ni.
B) O.
C) Al.
D) Si.
E) Fe.

F) D) and E)
G) C) and D)

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The mass of the atmosphere has been estimated to be 5.2 × 1021 g, while the average molar mass of atmospheric gases is 28.9 g/mol. If the concentration of carbon dioxide in the atmosphere is 360 ppm by volume, calculate the mass of this gas in the atmosphere, in billions of metric tons, bmt. (1 bmt = 1012 kg)

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Calcium oxide is added to molten iron in the production of carbon steel in order to


A) convert silicon and phosphorus oxides to slag which can be decanted from the molten steel.
B) serve as a scrubber to remove sulfur dioxide from the gases leaving the furnace.
C) remove any traces of acid which could weaken the steel.
D) add a small amount of oxygen to the steel to prevent corrosion and increase its strength.
E) create gangue.

F) A) and E)
G) B) and E)

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The process of converting metal sulfides to metal oxides is called


A) roasting.
B) smelting.
C) reduction.
D) leaching.
E) oxidation.

F) B) and C)
G) B) and E)

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Cryolite, Na3AlF6, is used in the electrolysis of aluminum oxide because


A) it is a good source of fluoride ions.
B) it reduces the energy requirement of the process, due to its low melting point.
C) it provides a source of fluorine, an oxidizing agent.
D) it provides a source of sodium, a reducing agent.
E) it is very soluble in water.

F) A) and E)
G) D) and E)

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Which one of the following species or compounds reacts at the cathode in the Hall-Héroult process?


A) Al2O3
B) Al(OH) 3
C) F-
D) AlF63-
E) C

F) All of the above
G) C) and E)

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The process that selectively extracts a metal from its ore, by dissolving it, is called


A) roasting.
B) leaching.
C) smelting.
D) flotation.
E) hydration.

F) A) and D)
G) C) and E)

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The alkali metals are isolated from non-aqueous systems. Why is this necessary?


A) The electrolysis of aqueous solutions of the alkali metals requires more energy than electrolysis of the molten salts.
B) The dissolved alkali earth halides are too reactive to be electrolyzed.
C) The aqueous metal ions are more difficult to reduce than water.
D) The reduction potentials of the alkali metals are more positive than the reduction potential of water.
E) The aqueous metal ions react violently with water.

F) A) and D)
G) C) and D)

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The leaching of gold can be represented by the equation 4Au(s) + O2(s) + 8CN-(aq) + 2H2O(l) 4Au(CN)2-(aq) + 4OH-(aq) In this reaction, identify the oxidant, the reductant and the oxidation numbers of the elements which change.

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The oxidant is O2, the reductan...

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Sulfide ores are frequently treated by flotation in order to concentrate them.

A) True
B) False

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True

The Downs cell is used in the production of


A) copper.
B) hydrogen.
C) iron.
D) magnesium.
E) sodium.

F) A) and D)
G) A) and B)

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What elements are alloyed to make stainless steel?


A) Fe and C
B) Fe and Mn
C) Fe and Ni
D) Cr and C
E) Fe, Cr, and Ni

F) D) and E)
G) All of the above

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E

Which of the following reactions is a good small-scale laboratory method for preparation of hydrogen?


A) CH4(g) + H2O(g) CO(g) + 3H2(g)
B) 3FeCl2(s) + 4H2O(g) Fe3O4(s) + 6HCl(g) + H2(g)
C) NaH(s) + H2O(l) NaOH(aq) + H2(g)
D) CO(g) + H2O (g) CO2(g) + H2(g)
E) None of the above methods is useful.

F) B) and E)
G) D) and E)

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Describe, and give reasons for, the fundamental bonding differences between transition metal sulfides and transition metal oxides.

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Transition metal oxides are ionic in nat...

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