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Define an acid according to the Arrhenius theory, and write a balanced equation to support this definition.

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An acid is a substance which c...

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Which one of the following is a strong acid?


A) H2CO3
B) H2SO3
C) H2SO4
D) H3PO4
E) CH3COOH

F) A) and B)
G) D) and E)

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Which of the following aqueous liquids is the most acidic?


A) 0.1 M Al(NO3) 3, Ka = 1 × 10-5
B) 0.1 M Be(NO3) 2, Ka = 4 × 10-6
C) 0.1 M Pb(NO3) 2, Ka = 3 × 10-8
D) 0.1 M Ni(NO3) 2, Ka = 1 × 10-10
E) pure water

F) All of the above
G) C) and D)

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The hydrated Al3+ ion, Al(H2O) 63+, is a weak acid in water. What are the products of its reaction with H2O? Al(H2O) 63+(aq) + H2O(l) ?


A) Al(H2O) 5OH2+(aq) + H3O+(aq)
B) Al(H2O) 6H4+(aq) + OH-( aq)
C) Al(H2O) 53+(aq) + 2H2O(l)
D) Al(H2O) 6OH2+(aq) + H3O+( aq)
E) Al(H2O) 62+(aq) + H3O+( aq)

F) A) and E)
G) C) and D)

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Which of the following pairs has the stronger acid listed first?


A) HBr, HI
B) HClO2, HClO3
C) H2SeO4, H2SeO3
D) HNO2, HNO3
E) HF, HCl

F) B) and D)
G) A) and B)

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The English are fond of soggy French fries ("chips") wrapped in old newspaper and generously drenched in vinegar, which is a 0.83 M solution of acetic acid. If the acetic acid in vinegar is 0.47% dissociated, calculate Ka for this acid.

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Kw = 1.0 × 10-14, regardless of temperature.

A) True
B) False

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All Brønsted-Lowry bases contain the hydroxide ion, OH-.

A) True
B) False

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What is the pH of a 0.0125 M NaOH solution?


A) 0.972
B) 1.903
C) 12.097
D) 13.028
E) none of the above

F) B) and D)
G) D) and E)

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The substance HCl is considered


A) a weak Arrhenius acid.
B) a weak Arrhenius base.
C) a strong Arrhenius acid.
D) a strong Arrhenius base.
E) a neutral compound.

F) A) and B)
G) A) and C)

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If the compound HX is a strong acid (where H is the acidic proton in this acid), then the ion X- is a weak base.

A) True
B) False

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Ammonium chloride is used as an electrolyte in dry cells. Which of the following statements about a 0.10 M solution of NH4Cl, is correct?


A) The solution is weakly basic.
B) The solution is strongly basic.
C) The solution is neutral.
D) The solution is acidic.
E) The values for Ka and Kb for the species in solution must be known before a prediction can be made.

F) B) and D)
G) B) and E)

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An aqueous solution is prepared by dissolving the salt formed by the neutralization of a weak acid by a weak base. Which statement about the solution is correct?


A) The solution is strongly basic.
B) The solution is weakly basic.
C) The solution is neutral.
D) The solution is acidic.
E) The values for Ka and Kb for the species in solution must be known before a prediction can be made.

F) A) and B)
G) None of the above

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All weak acids have strong conjugate bases.

A) True
B) False

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Which of the following is considered a Lewis acid?


A) CH3NH2
B) BCl3
C) F-
D) BF4-
E) CH4

F) B) and C)
G) A) and E)

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The ammonium ion, NH4+, is a weak acid.

A) True
B) False

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All Brønsted-Lowry bases have at least one lone pair of electrons.

A) True
B) False

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Which one of the following substances will give an aqueous solution of pH < 7?


A) KI
B) NH4Br
C) Na2CO3
D) CH3COONa
E) CH3OH

F) D) and E)
G) B) and D)

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Aqueous solutions of phosphoric acid and sodium nitrite are combined, and the following equilibrium is established. H3PO4(aq) + NO2-(aq) Aqueous solutions of phosphoric acid and sodium nitrite are combined, and the following equilibrium is established. H<sub>3</sub>PO<sub>4</sub>(aq)  + NO<sub>2</sub><sup>-</sup>(aq)    H<sub>2</sub>PO<sub>4</sub><sup>-</sup>(aq)  + HNO<sub>2</sub>(aq)  The equilibrium constant K<sub>c</sub> for this reaction is greater than one. Based on this information, which of the following statements is correct? A)  Phosphoric acid is a weaker acid than nitrous acid. B)  Nitrous acid is a weaker acid than water. C)  The nitrite anion is a weaker base than the dihydrogen phosphate anion. D)  The dihydrogen phosphate anion is a stronger acid than nitrous acid. E)  Phosphoric acid is a stronger acid than nitrous acid. H2PO4-(aq) + HNO2(aq) The equilibrium constant Kc for this reaction is greater than one. Based on this information, which of the following statements is correct?


A) Phosphoric acid is a weaker acid than nitrous acid.
B) Nitrous acid is a weaker acid than water.
C) The nitrite anion is a weaker base than the dihydrogen phosphate anion.
D) The dihydrogen phosphate anion is a stronger acid than nitrous acid.
E) Phosphoric acid is a stronger acid than nitrous acid.

F) A) and E)
G) A) and D)

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Which of the following acids has the lowest pH? 0.1 M HBO, pKa = 2.43 0) 1 M HA, pKa = 4.55 0) 1 M HMO, pKa = 8.23 0) 1 M HST, pKa = 11.89 Pure water


A) HA
B) HST
C) HMO
D) HBO
E) pure water

F) B) and C)
G) A) and B)

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