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Which of the following ions could exist in either the high-spin or low-spin state in an octahedral complex?


A) Sc3+
B) Ni2+
C) Mn2+
D) Ti4+
E) Zn2+

F) None of the above
G) B) and C)

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Which of the following is considered a bidentate ligand?


A) cyanide,CN-
B) thiocyanate,SCN-
C) oxalate,C2O42-
D) nitrite,NO2-
E) hydroxide,OH-

F) C) and E)
G) D) and E)

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All atoms of the first transition series of elements have the ground state electronic configuration [Ar]4s23dx,where x is an integer from 1 to 10.

A) True
B) False

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Which of the following should be the strongest reducing agent?


A) Fe
B) Ru
C) Os
D) Re
E) Cu

F) All of the above
G) A) and E)

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The compound K3[Fe(CN) 6] is used in calico printing and wool dyeing.Give its systematic name.


A) potassium iron(III) hexacyanate
B) tripotassium iron(III) hexacyanate
C) potassium hexacyanoferrate(III)
D) potassium hexacyanideferrate
E) None of these choices is correct.

F) A) and B)
G) A) and C)

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Consider the following octahedral complex structures,each involving ethylene diamine and two different,unidentate ligands X and Y. Consider the following octahedral complex structures,each involving ethylene diamine and two different,unidentate ligands X and Y.   Which,if any,of the following pairs are optical isomers? A) 1 and 2 B) 1 and 3 C) 1 and 4 D) 3 and 4 E) None of these choices is correct. Which,if any,of the following pairs are optical isomers?


A) 1 and 2
B) 1 and 3
C) 1 and 4
D) 3 and 4
E) None of these choices is correct.

F) A) and B)
G) A) and C)

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In the presence of a strong octahedral ligand field,the number of unpaired electrons in Co(III) will be


A) 0.
B) 2.
C) 4.
D) 6.
E) None of these choices is correct.

F) A) and E)
G) B) and C)

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Which of the following will be paramagnetic?


A) V5+
B) Ni2+
C) Mn7+
D) Ti4+
E) Zn

F) C) and D)
G) A) and E)

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What is the highest possible oxidation state for palladium,Pd?


A) +1
B) +2
C) +3
D) +4
E) +6

F) A) and B)
G) A) and E)

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If a solution absorbs green light,what is its likely color?


A) red
B) violet
C) orange
D) yellow
E) blue

F) A) and C)
G) C) and D)

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How many unpaired electrons will there be in a high-spin octahedral complex of Fe(II) ?


A) 0
B) 2
C) 4
D) 6
E) None of these choices is correct.

F) B) and E)
G) B) and C)

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a.How can the formation of a complex ion be described in terms of a theory of acids and bases? b.What is the essential requirement for a molecule or ion to act as a ligand?

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a.According to Lewis,in an acid-base rea...

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