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After the equivalence point, the titration curve of a weak acid is identical to that of a ________ ________.

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Which compound has the lowest solubility in pure water?


A) Ag2C2O4, Ksp = 1.0 × 10-11
B) PbCl2, Ksp = 1.7 × 10-5
C) FePO4, Ksp = 1.3 × 10-22
D) Ca3(PO4) 2, Ksp = 1.2 × 10-26
E) MgF2, Ksp = 6.9 × 10-9

F) A) and E)
G) None of the above

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Which will precipitate first when AgNO3 is added to a solution containing equal concentrations of Br-, Cl-, and I- ions?


A) AgBr
B) AgCl
C) AgI
D) AgNO3
E) No precipitate will form

F) B) and C)
G) A) and E)

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A buffer is prepared by adding 1.00 L of 1.0 M HCl to 750 mL of 1.5 M NaHCOO. What is the pH of this buffer? [Ka(HCOOH) = 1.7 × 10-4]


A) 2.87
B) 3.72
C) 3.82
D) 3.95
E) 4.66

F) A) and B)
G) A) and E)

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Calculate the minimum concentration of Cr3+ that must be added to 0.095 M NaF in order to initiate a precipitate of chromium(III) fluoride. [Ksp(CrF3) = 6.6 × 10-11]


A) 0.023 M
B) 0.032 M
C) 7.7 × 10-8 M
D) 2.9 × 10-9 M
E) 6.9 × 10-10 M

F) A) and D)
G) A) and B)

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A buffer is prepared by adding 150 mL of 1.0 M NaOH to 250 mL of 1.0 M NaH2PO4. How many moles of HCl must be added to this buffer solution to change the pH by 0.18 units?


A) 0.025 mol HCl
B) 0.063 mol HCl
C) 0.082 mol HCl
D) 0.50 mol HCl
E) 1.0 mol HCl

F) B) and D)
G) A) and B)

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When a weak acid is titrated with a weak base, the pH at the equivalence point


A) is greater than 7.0.
B) is equal to 7.0.
C) is less than 7.0.
D) is determined by the magnitudes of Ka and Kb.
E) depends on the pKa of the indicator.

F) B) and D)
G) A) and E)

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Which best describes the pH at the equivalence point of a titration of a weak base with a strong acid?


A) Less than zero
B) Between 0 and 7
C) Close to 7.0
D) Between 7 and 14
E) Greater than 14

F) A) and B)
G) A) and C)

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The solubility of magnesium phosphate is 2.27 × 10-3 g/1.0 L of solution. What is the Ksp for Mg3(PO4) 2?


A) 7.46 × 10-11
B) 2.68 × 10-9
C) 5.19 × 10-24
D) 4.80 × 10-26
E) 1.20 × 10-26

F) D) and E)
G) A) and B)

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The solubility of lead(II) iodide is 0.064 g/100 mL at 20°C. What is the solubility product for lead(II) iodide?


A) 1.1 × 10-8
B) 2.7 × 10-9
C) 1.1 × 10-11
D) 2.7 × 10-12
E) 1.1 × 10-3

F) C) and E)
G) A) and E)

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A(n) ________ is a measure of the tendency of a metal ion to form a particular complex ion and is the equilibrium constant for the complex ion formation.

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formation constant o...

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What molar ratio of CH3COOH to CH3COONa should be used in order to prepare an acetic acid / sodium acetate buffer solution with a pH of 4.00 ± 0.02? [Ka(CH3COOH) = 1.8 × 10-5]


A) 0.18
B) 0.84
C) 1.2
D) 5.6
E) 0.10

F) A) and C)
G) A) and E)

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A 50.0-mL sample of a 0.100 M solution of a weak acid HA has an equilibrium pH of 4.00. After 1.0 × 10-3mol of a substance X is added to the solution, it is observed that the pH of the solution increases. What might be true about substance X? I. X might be a strong base that partially neutralized some weak acid. II) X might be a strong acid that made the solution more acidic. III) X might be a soluble ionic compound containing the anion A-.


A) I only
B) II only
C) III only
D) I or III
E) II or III

F) None of the above
G) A) and D)

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Which is the best choice for preparing a buffer with a pH of 3.5?


A) C5H5O5COOH, Ka = 4.0 × 10-6
B) HOC6H4OCOOH, Ka = 1.0 × 10-3
C) HBrO, Ka = 2.3 × 10-9
D) C6H4(COOH) 2, Ka = 2.9 × 10-4
E) CH3COOH, Ka = 1.8 ×10-5

F) All of the above
G) None of the above

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A ________ helps maintain a constant pH even after the addition of acid or base.

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Which compound has the highest solubility in pure water?


A) Ag2C2O4, Ksp = 1.0 × 10-11
B) PbCl2, Ksp = 1.7 × 10-5
C) CaSO4, Ksp = 2.4 × 10-5
D) Ca3(PO4) 2, Ksp = 1.2 × 10-26
E) MgF2, Ksp = 6.9 × 10-9

F) C) and E)
G) C) and D)

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Which pair of substances is capable of forming a buffer in aqueous solution?


A) H3PO4, Na3PO3
B) HNO3, NaNO3
C) HCl, NaCl
D) H2CO3, NaNO2
E) CH3COOH, CH3COONa

F) A) and E)
G) D) and E)

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Explain the effect on the ionization of the acetic acid when sodium acetate is added to a solution of acetic acid? CH3COOH(aq) Explain the effect on the ionization of the acetic acid when sodium acetate is added to a solution of acetic acid? CH<sub>3</sub>COOH(aq)   H<sup>+</sup>(aq) + CH<sub>3</sub>COO<sup>-</sup>(aq) H+(aq) + CH3COO-(aq)

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The equilibrium shif...

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The molar solubility of magnesium carbonate is 1.8 × 10-4 mol/L. What is Ksp for this compound?


A) 1.8 × 10-4
B) 3.6 × 10-4
C) 1.3 × 10-7
D) 3.2 × 10-8
E) 2.8 × 10-14

F) C) and D)
G) B) and D)

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Which of the following is an exact or approximate value of the pH at the equivalence point of a titration of a strong acid with a strong base?


A) 14.0
B) 7.0
C) 3.5
D) 1.0
E) 0.0

F) B) and E)
G) A) and B)

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