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The value of E °\degree cell for the reaction  The value of E  \degree <sub>cell</sub> for the reaction   is 1.59 V. Calculate  \Delta G  \degree  for the reaction. A)  -921 kJ B)  -767 kJ C)  -460 kJ D)  -307 kJ E)  None of these choices is correct. is 1.59 V. Calculate Δ\Delta G °\degree for the reaction.


A) -921 kJ
B) -767 kJ
C) -460 kJ
D) -307 kJ
E) None of these choices is correct.

F) B) and C)
G) A) and C)

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The lead-acid battery is an example of a secondary battery.

A) True
B) False

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Which of the following statements about voltaic and electrolytic cells is correct?


A) The anode will definitely gain weight in a voltaic cell.
B) Oxidation occurs at the cathode of both cells.
C) The free energy change, Δ\Delta G, is negative for the voltaic cell.
D) The electrons in the external wire flow from cathode to anode in an electrolytic cell.
E) None of these choices is correct.

F) B) and C)
G) C) and D)

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Consider the reaction: CuO(s) + H2(g) \rightarrow Cu(s) + H2O(l) In this reaction, which substances are the oxidant and reductant, respectively?


A) CuO and H2
B) H2 and CuO
C) CuO and Cu
D) H2O and H2
E) None of these choices is correct.

F) B) and C)
G) None of the above

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A voltaic cell prepared using zinc and iodine has the following cell notation.  A voltaic cell prepared using zinc and iodine has the following cell notation.   Which of the following equations correctly represents the balanced, spontaneous cell reaction? A)  2I¯(aq)  + Zn<sup>2+</sup>(aq)   \rightarrow  I<sub>2</sub>(s)  + Zn(s)  B)  I<sub>2</sub>(s)  + Zn(s)   \rightarrow  2I¯(aq)  + Zn<sup>2+</sup>(aq)  C)  2I¯(aq)  + Zn(s)   \rightarrow I<sub>2</sub>(s)  + Zn<sup>2+</sup>(aq)  D)  I<sub>2</sub>(s)  + Zn<sup>2+</sup>(aq)   \rightarrow  2I¯(aq)  + Zn(s)  E)  None of these choices, since graphite must be in the equation. Which of the following equations correctly represents the balanced, spontaneous cell reaction?


A) 2I¯(aq) + Zn2+(aq) \rightarrow I2(s) + Zn(s)
B) I2(s) + Zn(s) \rightarrow 2I¯(aq) + Zn2+(aq)
C) 2I¯(aq) + Zn(s) \rightarrow I2(s) + Zn2+(aq)
D) I2(s) + Zn2+(aq) \rightarrow 2I¯(aq) + Zn(s)
E) None of these choices, since graphite must be in the equation.

F) C) and E)
G) B) and E)

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A concentration cell is based on the aqueous reaction A concentration cell is based on the aqueous reaction   The cell consists of copper electrodes dipping into solutions of Cu<sup>2+</sup> ions. The anions present are sulfate ions. Write the shorthand cell notation for this cell. The cell consists of copper electrodes dipping into solutions of Cu2+ ions. The anions present are sulfate ions. Write the shorthand cell notation for this cell.

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Calculate E °\degree cell and indicate whether the overall reaction shown is spontaneous or nonspontaneous.  Calculate E \degree <sub>cell</sub> and indicate whether the overall reaction shown is spontaneous or nonspontaneous.   Overall reaction:   A)  E \degree <sub>cell</sub> = -1.00 V, nonspontaneous B)  E \degree <sub>cell</sub> = -1.00 V, spontaneous C)  E \degree <sub>cell</sub> = 1.00 V, nonspontaneous D)  E \degree <sub>cell</sub> = 1.00 V, spontaneous E)  E \degree <sub>cell</sub> = -0.23 V, nonspontaneous Overall reaction:  Calculate E \degree <sub>cell</sub> and indicate whether the overall reaction shown is spontaneous or nonspontaneous.   Overall reaction:   A)  E \degree <sub>cell</sub> = -1.00 V, nonspontaneous B)  E \degree <sub>cell</sub> = -1.00 V, spontaneous C)  E \degree <sub>cell</sub> = 1.00 V, nonspontaneous D)  E \degree <sub>cell</sub> = 1.00 V, spontaneous E)  E \degree <sub>cell</sub> = -0.23 V, nonspontaneous


A) E °\degree cell = -1.00 V, nonspontaneous
B) E °\degree cell = -1.00 V, spontaneous
C) E °\degree cell = 1.00 V, nonspontaneous
D) E °\degree cell = 1.00 V, spontaneous
E) E °\degree cell = -0.23 V, nonspontaneous

F) A) and D)
G) A) and C)

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A salt bridge provides a path for electrons to move between the anode and cathode compartments of a voltaic cell.

A) True
B) False

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When metal A is placed in a solution of metal ions B2+, a reaction occurs between A and B2+, and metal ions A2+ appear in the solution. When metal B is placed in acid solution, gas bubbles form on its surface. When metal A is placed in a solution of metal ions C2+, no reaction occurs. Which of the following reactions would not occur spontaneously?


A) C(s) + 2H+(aq) \rightarrow H2(g) + C2+(aq)
B) C(s) + A2+(aq) \rightarrow A(s) + C2+(aq)
C) B(s) + C2+(aq) \rightarrow C(s) + B2+(aq)
D) A(s) + 2H+(aq) \rightarrow H2(g) + A2+(aq)
E) B(s) + 2H+(aq) \rightarrow H2(g) + B2+(aq)

F) A) and C)
G) A) and B)

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What product forms at the cathode during the electrolysis of molten lithium iodide?


A) Li+(l)
B) Li(l)
C) I¯(l)
D) I2(g)
E) I3¯(l)

F) B) and E)
G) B) and C)

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A voltaic cell consists of a Mn/Mn2+ electrode (E °\degree = -1.18 V) and a Fe/Fe2+ electrode (E °\degree = -0.44 V) . Calculate [Fe2+] if [Mn2+] = 0.050 M and Ecell = 0.78 V at 25 °\degree C.


A) 0.040 M
B) 0.24 M
C) 1.1 M
D) 1.8 M
E) None of these choices is correct.

F) B) and D)
G) None of the above

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A cell can be prepared from copper and tin. What is the E °\degree cell for the cell that forms from the following half-reactions?  A cell can be prepared from copper and tin. What is the E \degree <sub>cell</sub> for the cell that forms from the following half-reactions?   A)  0.47 V B)  0.21 V C)  -0.21 V D)  -0.47 V E)  0.42 V


A) 0.47 V
B) 0.21 V
C) -0.21 V
D) -0.47 V
E) 0.42 V

F) B) and C)
G) A) and B)

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When the following redox equation is balanced with smallest whole number coefficients, the coefficient for zinc will be _____. When the following redox equation is balanced with smallest whole number coefficients, the coefficient for zinc will be _____.   A)  2 B)  7 C)  8 D)  16 E)  None of these choices is correct.


A) 2
B) 7
C) 8
D) 16
E) None of these choices is correct.

F) B) and D)
G) B) and C)

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A battery is considered "dead" when:


A) Q < 1
B) Q = 1
C) Q > 1
D) Q = K
E) Q/K = 0

F) B) and C)
G) A) and E)

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When the following redox equation is balanced with smallest whole number coefficients, the coefficient for the hydrogen sulfate ion will be ______. When the following redox equation is balanced with smallest whole number coefficients, the coefficient for the hydrogen sulfate ion will be ______.   A)  1 B)  3 C)  4 D)  8 E)  None of these choices is correct.


A) 1
B) 3
C) 4
D) 8
E) None of these choices is correct.

F) A) and E)
G) A) and D)

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Oxidation occurs at the cathode of a galvanic cell, but at the anode of an electrolytic cell.

A) True
B) False

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For the reaction occurring in a voltaic (galvanic) cell, Δ\Delta G > 0.

A) True
B) False

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What product forms at the anode during the electrolysis of molten NaBr?


A) Na+(l)
B) Na(l)
C) Br¯(l)
D) Br3¯(l)
E) Br2(g)

F) B) and C)
G) C) and E)

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A concentration cell is based on the aqueous reaction A concentration cell is based on the aqueous reaction   The cell consists of copper electrodes dipping into solutions of Cu<sup>2+</sup> ions. The anions present are sulfate ions. Draw a neat diagram to represent this cell, showing and labeling all necessary components including: anode, cathode, electron flow, cation flow and anion flow. The cell consists of copper electrodes dipping into solutions of Cu2+ ions. The anions present are sulfate ions. Draw a neat diagram to represent this cell, showing and labeling all necessary components including: anode, cathode, electron flow, cation flow and anion flow.

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Consider the reaction of iodine with manganese dioxide: 3I2(s) + 2MnO2(s) + 8OH¯(aq)  Consider the reaction of iodine with manganese dioxide:  3I<sub>2</sub>(s)  + 2MnO<sub>2</sub>(s)  + 8OH¯(aq)    6I¯(aq)  + 2MnO<sub>4</sub>¯(aq)  + 4H<sub>2</sub>O(l)  The equilibrium constant for the overall reaction is 8.30 *10¯<sup>7</sup>. Calculate E \degree <sub>cell</sub> for the reaction at 25 \degree C. A)  -0.36 V B)  -0.18 V C)  -0.12 V D)  -0.060 V E)  None of these choices is correct. 6I¯(aq) + 2MnO4¯(aq) + 4H2O(l) The equilibrium constant for the overall reaction is 8.30 *10¯7. Calculate E °\degree cell for the reaction at 25 °\degree C.


A) -0.36 V
B) -0.18 V
C) -0.12 V
D) -0.060 V
E) None of these choices is correct.

F) C) and D)
G) C) and E)

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