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Ionic hydrides do not have exact (stoichiometric) formulas.

A) True
B) False

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Which of the following elements exists in allotropic forms?


A) silicon
B) germanium
C) tin
D) lead
E) xenon

F) All of the above
G) A) and E)

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Certain Period 2 elements exhibit behaviors similar to Period 3 elements immediately below and to the right. One of these interesting diagonal relationships occurs between lithium and magnesium. Which of the following is one of their similarities?


A) They both form insoluble carbonate salts.
B) Both elements are important in treating manic-depression.
C) Their first ionization energies are almost equal.
D) Their densities are very similar.
E) They both form organic compounds with polar covalent bonds from the metal to hydrocarbon group.

F) All of the above
G) B) and E)

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Which one of the following elements is likely to exhibit the most violent and rapid reaction with water?


A) Na
B) Rb
C) Mg
D) Sr
E) Cl2

F) B) and D)
G) All of the above

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Which of the following oxides will give the most basic solution when dissolved in water?


A) SO2
B) CO2
C) K2O
D) P4O10
E) SO3

F) C) and D)
G) B) and D)

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Ozone is both a pollutant and a natural component of the atmosphere.

A) True
B) False

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The polymers containing silicon differ from polymers of carbon in which of the following ways?


A) Silicon-based polymers are larger molecules than carbon-based polymers.
B) Silicon-based polymers generally have a repeating silicon-oxygen link while carbon-based polymers can have carbon-carbon links.
C) Silicon-based polymers generally have inorganic elements attached to the chain while carbon-based polymers generally have organic groups attached.
D) Silicon-based polymers tend to be rigid while carbon-based polymers are generally flexible.
E) Silicon forms stronger bonds than carbon.

F) A) and B)
G) C) and D)

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The atomic radius of sodium is 186 pm and of chlorine is 100 pm. The ionic radius for Na+ is 102 pm and for Cl- is 181 pm. In going from Na to Cl in Period 3, why does the atomic radius decrease while the ionic radius increases?


A) The inner electrons in the sodium cation shield its valence electrons more effectively than the inner electrons in the chloride anion do.
B) The inner electrons shield the valence electrons more effectively in the chlorine atom than in the chloride anion.
C) The outermost electrons in chloride experience a smaller effective nuclear charge than those in the sodium cation do.
D) The outermost electrons in chloride experience a larger effective nuclear charge than those in the sodium cation do.
E) Monatomic ions are bigger than the atoms from which they are formed.

F) A) and B)
G) B) and D)

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Which of the following would you predict to have the greatest thermal stability?


A) AsAt3
B) AsI3
C) AsBr3
D) AsCl3
E) AsF3

F) B) and D)
G) B) and C)

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Predict the products for the following set of reactants. Bi(s) + Cl2(g) →


A) BiCl
B) BiCl2
C) BiCl3
D) BiCl4
E) BiCl5

F) A) and C)
G) D) and E)

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Oxygen gas (O2) is paramagnetic, but ozone (O3) is diamagnetic.

A) True
B) False

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Sodium hypochlorite is used


A) in chemical analysis.
B) as an oxidizer in rocket fuels.
C) as a disinfectant.
D) in the manufacture of steel.
E) as a detergent.

F) A) and E)
G) A) and B)

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The smallest ionization energies are found in the ____________ ___________ region of the periodic table.


A) upper right
B) upper left
C) lower right
D) lower left
E) transition element (d-block)

F) B) and E)
G) All of the above

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What are the products of the reaction of potassium hydride and water? KH(s) + H2O(l) →


A) K(s) + H2(g) + OH-(aq)
B) K(s) + H2(g) + O2(g)
C) KOH(s) + O2(g)
D) K+(aq) + H2(g) + O2(g)
E) K+(aq) + H2(g) + OH-(aq)

F) D) and E)
G) B) and C)

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Predict the products for the reaction of the following set of reactants. CaO(s) + H2O(l) →


A) Ca2+(aq) + OH-(aq) + H2(g)
B) Ca2+(aq) + H2(g) + O2(g)
C) Ca2+(aq) + H3O+(aq)
D) Ca(OH) 2(s)
E) CaH2(s) + O2(g)

F) B) and C)
G) B) and E)

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What are the products of the following reaction of strontium hydride and water? SrH2(s) + H2O(l) →


A) Sr2+(aq) + H2(g) + O2(g)
B) Sr2+(aq) + H2(g) + OH-(aq)
C) Sr(s) + H2(g) + OH-(aq)
D) Sr(s) + H3O+(aq)
E) None of these choices are correct.

F) B) and C)
G) A) and E)

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The basic character of the binary oxides XmOn


A) is greatest when X has a low atomic number.
B) is greatest when X is a nonmetal.
C) increases as the oxidation number of X increases.
D) increases as the oxidation number of X decreases.
E) is unaffected by the oxidation number of X.

F) A) and B)
G) A) and C)

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Certain Period 2 elements exhibit behaviors similar to Period 3 elements immediately below and to the right. One of the interesting diagonal relationships occurs between boron and silicon. Which of the following is one of their similarities?


A) Both exhibit electrical properties of a conductor.
B) The oxoanions of both elements occur in extended ionic networks.
C) Both elements form compounds (boranes and silanes) that are good oxidizing agents.
D) Boric acid and silicic acid occur in layers with widespread hydrogen bonding.
E) Both elements are unusually soft solids.

F) B) and E)
G) A) and B)

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Predict the products for the reaction of the following set of reactants. (CH3) 3Ga(g) + AsH3(g) →


A) (CH3) 3As(g) + GaH3(g)
B) CH4(g) + GaAs(s)
C) CH3CH3(g) + GaAs(s)
D) CH4(g) + H2GaAs(s)
E) CH3H(g) + GaAs(s)

F) B) and D)
G) A) and E)

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The elements from Groups 1A(1) and 2A(2) are


A) strong acids.
B) strong bases.
C) amphoteric.
D) strong oxidizing agents.
E) strong reducing agents.

F) B) and C)
G) B) and E)

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